Project Grant 2154079
- This CAREER Project Grant, awarded by the National Science Foundation's (NSF) Mathematical and Physical Sciences program (CFDA 47.049), provides $785,000 in funding to Professor Pier Alexandre Champagne at the New Jersey Institute of Technology (NJIT) to advance the chemical understanding of reactive sulfur species. The project employs a combination of experimental and computational techniques to: 1) access new synthetic donors of reactive sulfur species, 2) use these donors to probe the...
- This $525,000 Project Grant award from the National Science Foundation (NSF) Mathematical and Physical Sciences program (CFDA 47.049) supports Professor Julia Laskin at Purdue University to conduct fundamental research on the reactivity of complex metal ion compounds deposited onto model surfaces. The research aims to develop a generalizable approach for preparing and studying well-defined solid-liquid interfaces to gain molecular-level insights into surface-mediated chemical transformations...
- This federal Project Grant award from the Division of Chemistry of the National Science Foundation (CFDA 47.049 - Mathematical and Physical Sciences) is providing $240,000 to support a research project led by Professors David Stuart and Theresa McCormick at Portland State University. The project aims to study the properties and reactivity of a class of chemical compounds called aryl "onium" species, which are used as versatile building blocks for synthesizing molecules with aromatic...
- This Project Grant award of $510,759 from the National Science Foundation (NSF) Division of Chemistry supports a research collaboration led by Professors Andrew Mitchell of Illinois State University and Dean Tantillo of UC-Davis. The goal is to develop new chemical reactions with connections to biology, medicine, physics, materials, and environmental sustainability. Key products include: Advancing oxidopyrylium-based [5+2] cycloaddition reactions to construct important heterocyclic small...
- The National Science Foundation (NSF) Chemical Synthesis Program awarded a $450,000 Project Grant to Professor William Chain at the University of Delaware (UDE) to develop new classes of reactions with aromatic compounds. The goal is to exploit weak bonds and temporarily elevate the reactivity of normally inert chemical compounds to facilitate the formation of a wide array of new carbon-based bonds, forging new cyclic frameworks that have applications in industrial, chemical, and medical...
- Professor Kutateladze of the University of Denver will use a $575,000 National Science Foundation Project Grant from the Mathematical and Physical Sciences program (CFDA 47.049) to further develop photoassisted approaches for the synthesis of complex heterocyclic molecules with potentially useful therapeutic properties. Over a three-year period from September 2023 through August 2026, his research aims to expand the synthetic photochemistry toolbox, specifically excited state intramolecular...
- The National Science Foundation (NSF) Chemical Synthesis Program has awarded a $550,000 Project Grant to Professor Jon Njardarson of the University of Arizona. The grant supports the development of new asymmetric anionic reaction cascades that leverage readily available feedstock materials and negatively charged reaction partners to produce higher-value fine chemical products. Key objectives include in situ trapping of lithium enamides to expand product types, as well as the formation of...
- The University of Illinois received a $500,000 Project Grant award from the National Science Foundation Division of Chemistry to support research on the "Reactions of Arynes and Other Reactive Intermediates" from July 1, 2021 to June 30, 2024. Under the award, the University will conduct research to increase understanding of major problems confronting the Nation in the area of chemical reactivity and synthesis through investigation of highly reactive chemical intermediates....
- The National Science Foundation (NSF) Chemical Synthesis Program awarded a $575,000 Project Grant to the University of Kansas Center for Research Inc. to develop new photochemical reactions for creating valuable and structurally complex molecules efficiently and selectively. The project, titled "Exploiting Mechanistic Knowledge to Develop Selective and Robust Synthetic N,π*-Star Photochemistry," aims to (1) generate reactive ylides from strained rings through light-induced sensitized...
- The National Science Foundation (NSF) is providing a $600,000 Project Grant under the Mathematical and Physical Sciences program (CFDA 47.049) to the Massachusetts Institute of Technology (MIT) for a 4-year research project led by Professor Alexander Radosevich. The project aims to develop inexpensive, earth-abundant chemical catalysts capable of enabling novel bond-making and bond-breaking reactions. Specific research areas include using proton-coupled electron transfer (PCET) to activate C-H...
This three-year, $525,000 Project Grant from the National Science Foundation's Division of Chemistry and Mathematical and Physical Sciences program will support research into aryloxenium cations. Professors Hilkka Kenttamaa and John Nash of Purdue University will investigate these highly reactive compounds that serve as key intermediates in important chemical and biological reactions like phenol oxidation, thermoplastic generation, and dehaloperoxidase-mediated dehalogenation. While implicated in fields as diverse as astrochemistry and industrial synthesis, aryloxenium cations remain poorly understood due to challenges generating and studying them in solution. The researchers will utilize gas-phase ion-molecule reactions and action spectroscopy in ion trap mass spectrometers to explore aryloxenium ion structures, reactivities with different reagents, and kinetic properties. Quantum chemical calculations will complement experimental studies. Insights gained will facilitate rational utilization of these cations and design of tailored species for applications. The project also aims to enhance graduate and undergraduate scientific training, including from underrepresented groups, through research experiences and industry/government internships.
Mod # | Description | ReasonForModification | Federal Obligation | Date |
|---|---|---|---|---|
| Not listed | $343.4k | 8/6/22 | ||
| Not listed | $181.6k | 4/21/22 |