Project Grant 2512362

Award Date 1/1/25
Completion Date 12/31/28
Dollars Obligated $600K
Federal Grant Program
47.049
Assistance Type
Project Grant
Place of Performance
Cambridge, MA 02139, USA
Similar Awards
The National Science Foundation Division of Chemistry awarded a three-year Project Grant totaling $600,000 to the Massachusetts Institute of Technology under the Mathematical and Physical Sciences federal grant program (CFDA 47.049). The grant supports research by Dr. Alexander Radosevich and his team to develop new metal-phosphorus complexes as homogeneous catalysts for small molecule conversion chemistry. Specifically, the grant funding will allow Dr. Radosevich's lab to pursue experiments...
This $525,000 Project Grant from the National Science Foundation's Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), will fund research at Boston College on metalloradical catalysis for selective radical reactions from July 1, 2022 to June 30, 2025. Professor Peter Zhang and his team will develop new catalytic systems using earth-abundant transition metals like cobalt to mediate one-electron radical reactions as a more sustainable alternative to...
Massachusetts Institute of Technology (MIT) received a three-year $575,000 Project Grant from the National Science Foundation's (NSF) Mathematical and Physical Sciences program (CFDA 47.049) to conduct research on the synthesis of phosphorus-containing small molecules with relevance to identifying interstellar molecules. Professor Christopher Cummins of MIT's Chemistry Department will synthesize molecules such as triphosphatetrahedrane, phosphorus mononitride, and phosphiranes derivatives for...
This $180,000 Project Grant award from the National Science Foundation (NSF) Mathematical and Physical Sciences program (CFDA 47.049) supports a collaborative research project to study new approaches to catalysis and electrochemistry for the synthesis of biaryl molecules useful in polymers and agriculture. Professors Daniel Weix and Shannon Stahl of the University of Wisconsin-Madison, Professor Mohammad Rafiee of the University of Missouri-Kansas City, and Professor Robert Paton of Colorado...
The Massachusetts Institute of Technology (MIT) received a $484,257 Project Grant award from the National Science Foundation (NSF) under the Mathematical and Physical Sciences Grant Program (CFDA 47.049) to develop new synthetic methods for low-valent boracyclic materials with unusual bonding properties for use in optoelectronic applications. Over a three-year period from May 2023 through March 2026, MIT researchers led by Dr. Robert Gilliard will synthesize stable open-shell boron radicals...
This $550,000 Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences program (CFDA 47.049) supports a research project led by Shuming Chen at Oberlin College. The project aims to develop computational models to better understand and enhance the selectivity of transition metal-catalyzed reactions that can functionalize strong covalent bonds, such as carbon-carbon and carbon-hydrogen bonds. This research has wide-ranging implications for advancing...
This $375,000 Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences (CFDA 47.049) program supports a collaborative research effort between the University of Michigan and the University of Colorado Boulder. The goal is to understand how surface-bound organic ligands affect the selectivity and performance of supported metal catalysts for the direct synthesis of hydrogen peroxide. The research team, led by Professors Eranda Nikolla and Will Medlin, will...
The National Science Foundation (NSF) awarded a $600,000 Project Grant under the Mathematical and Physical Sciences (CFDA 47.049) program to the Massachusetts Institute of Technology (MIT) for a research project titled "Directing Hydrogen Transfer via Pd Electrochemical Double Cell Polarization." The project, led by Professor Yogesh Surendranath, aims to develop a new approach for controlling the use of hydrogen in chemical reactions by combining electrical and thermal energy inputs....
This $650,000 Project Grant awarded by the National Science Foundation's (NSF) Mathematical and Physical Sciences program (CFDA 47.049) funds an industrial-academic collaboration between Princeton University and the Merck Catalysis Laboratory. The goal is to develop new sustainable catalytic methods for the large-scale synthesis of pharmaceutical drugs using earth-abundant metals like iron, cobalt, and nickel instead of rare precious metals. The research aims to identify viable catalytic...
Under a $529,170 award from the National Science Foundation's (NSF) Mathematical and Physical Sciences (MPS) program (CFDA 47.049), Professor Robert Paton and his research team at Colorado State University (CSU) will develop new computational workflows to accelerate the discovery and optimization of highly selective catalysts. The project aims to advance mechanistic understanding and establish new quantitative descriptors for three key catalyst and ligand classes - hydrogen-bond donors,...

This $600,000 Project Grant award from the National Science Foundation (NSF)'s Division of Chemistry, under the Mathematical and Physical Sciences Federal Grant Program (CFDA 47.049), supports research led by Professor Alexander Radosevich at the Massachusetts Institute of Technology (MIT). The project aims to develop new earth-abundant, redox-active organophosphorus catalysts capable of enabling novel bond cleavage and atom abstraction reactions via proton-coupled electron transfer (PCET) mechanisms. The expected outcomes include: 1) improved understanding of structure-reactivity relationships in multisite PCET reactions, 2) a rigorous rationale for the selectivity of observed H-atom abstraction reactions, and 3) new practical catalytic methods for constructing and functionalizing complex organic molecules through homolytic bond activation. This collaborative research also involves Dr. Sami Lakhdar at the Université Paul Sabatier Toulouse in France as part of a joint activity between NSF and the French Agence Nationale de la Recherche.

Generated 5/13/25, 3:11 AM