This three-year, $480,000 Project Grant from the National Science Foundation's Division of Chemistry and Mathematical and Physical Sciences program will support the development of sustainable catalysts and dehydrocoupling chemistry at Arizona State University. Principal Investigator Ryan J. Trovitch will study trends in earth-abundant metal catalysts to synthesize value-added chemicals and polymers more efficiently. Initial work will target precursors for semiconductor manufacturing. The project...
The National Science Foundation Division of Chemistry awarded Georgia Southern University Research & Service Foundation Inc. a $417,216 Project Grant under the Mathematical and Physical Sciences federal grant program (CFDA 47.049) to support fundamental research developing new octahedral ruthenium(II) olefin hydroarylation catalysts from July 1, 2022 to June 30, 2025. Professor Brandon Quillian of Georgia Southern University-Armstrong Campus will pursue the development of transition...
This Project Grant from the National Science Foundation Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), provides $353,295 to the University of Tennessee from August 1, 2022 to July 31, 2025. The funding supports research by Dr. Sirius Laursen and students to develop inexpensive, earth-abundant catalysts from non-noble metal intermetallic compounds for the conversion of waste from biomass processing into valuable diols and olefins. Through quantum...
This $456,907 project grant from the National Science Foundation's Mathematical and Physical Sciences program will fund research into metal-free bond activation using redox-active carborane clusters. Principal Investigator Dmitry Peryshkov of the University of South Carolina will synthesize cluster compounds of boron, carbon, phosphorus and hydrogen that can donate and accept electrons to cycle through two-electron redox states. The compounds' redox activity will be utilized to enable bond...
Through a $575,000 National Science Foundation (NSF) Mathematical and Physical Sciences (CFDA 47.049) award, Cornell University will investigate ways of utilizing more abundant 1st row transition metals as alternatives to expensive precious metals commonly used in catalytic chemistry. The primary objective is to develop methods for modifying 1st row transition metal compounds with ligands to provide the chemical reactivity and covalency typically associated with 2nd and 3rd row transition...
Through a $497,704 Project Grant award from the National Science Foundation's Chemical Catalysis program (CFDA 47.049 Mathematical and Physical Sciences), Professor Ming-Yu Ngai of Purdue University is conducting research to develop new sustainable catalytic processes leveraging first-row transition metals. The project aims to expand understanding of radical migration mechanisms and enable site- and stereoselective functionalization of carbohydrates and other small molecule building blocks....
This $600,000 Project Grant was awarded by the National Science Foundation (NSF) under the Mathematical and Physical Sciences (CFDA 47.049) federal grant program. The grant supports Professor Alexander Radosevich of the Massachusetts Institute of Technology (MIT) in studying new molecular catalysts composed of earth-abundant elements like iron and phosphorus. The research aims to develop cost-effective catalysts capable of enabling challenging bond cleavage and atom abstraction reactions through...
This $525,000 Project Grant from the National Science Foundation's Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), will fund research at Boston College on metalloradical catalysis for selective radical reactions from July 1, 2022 to June 30, 2025. Professor Peter Zhang and his team will develop new catalytic systems using earth-abundant transition metals like cobalt to mediate one-electron radical reactions as a more sustainable alternative to...
This $481,040 Project Grant awarded by the National Science Foundation's (NSF) Division of Chemistry is supporting research at the University of Virginia (UVA) to improve the activity of manganese-based catalysts for the oxygen reduction reaction. The research aims to develop design principles for more effective manganese catalysts that can match the performance of other transition metals for this reaction, which is critical for renewable energy technologies like fuel cells. The key focus...
This Project Grant award from the National Science Foundation (CFDA 47.049 - Mathematical and Physical Sciences) provides $643,347.00 to the University of Alabama-Tuscaloosa to develop computational tools that empower the design of efficient molecular catalysts. The key products and services to be delivered under this 5-year award include: Using high-performance computational screening to identify optimal catalyst structures, compositions, and kinetics to increase activity, selectivity, and...