Project Grant 2153757

Award Date 8/1/22
Completion Date 7/31/25
Dollars Obligated $545K
Federal Grant Program
47.049
Assistance Type
Project Grant
Place of Performance
La Jolla, CA 92093, USA
Similar Awards
This $575,000 Project Grant from the National Science Foundation's Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), will fund research at the University of California, San Diego to synthesize and study the reactivity of unusual main group elements stabilized by transition metal isocyanide complexes, from July 1, 2023 to June 30, 2026. Specifically, Professor Joshua S. Figueroa will manipulate boron monofluoride and diphosphorus molecules, which are...
This $550,000 Project Grant from the National Science Foundation Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), supports research at Texas A&M University from August 1, 2022 to July 31, 2025. Professor François Gabbaï and his team will investigate the synthesis and coordination chemistry of novel ambiphilic ligands featuring a carbenium ion positioned next to a phosphine- or carbene-based metal-binding site. When coordinated to late transition...
This $600,000 Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences (CFDA 47.049) program will support research at the University of Michigan and Trinity University to investigate the structural and electronic properties of high-valent cobalt, nickel, and copper-oxo complexes. The project aims to improve understanding of how metal-oxo versus metal-oxyl character impacts the stability and reactivity of these unstable, yet potentially useful,...
This $201,993 project grant award from the National Science Foundation's (NSF) Division of Chemistry, under the Mathematical and Physical Sciences program (CFDA 47.049), supports Professor Neal Mankad of the University of Illinois Chicago in studying earth-abundant metal complexes that can efficiently harvest energy from light to catalyze chemical transformations. The research team will create bimetallic reaction centers encapsulated by naturally occurring sugar molecules called cyclodextrins,...
The National Science Foundation (NSF) Division of Chemistry has awarded a 3-year, $575,000 Project Grant to Professor Alan Heyduk at the University of California, Irvine (UC Irvine) under the NSF's Mathematical and Physical Sciences program (CFDA 47.049). The grant will support Professor Heyduk's research to design and synthesize innovative, redox-active ligand platforms that can enhance the electronic properties and reactivity patterns of transition metal coordination complexes. This research...
The National Science Foundation (NSF) Division of Chemistry awarded a $550,000 Project Grant under the Mathematical and Physical Sciences (CFDA 47.049) program to the University of North Carolina at Chapel Hill (UNC-CH) for a 3-year project. The objective is to establish light-activated reactions that form transition metal hydride complexes, which are critical for producing fuels and commodity chemicals. The research activities will study the electronic structure and photochemistry of...
The National Science Foundation Division of Chemistry awarded a $366,433 Project Grant to Cornell University to conduct collaborative research on the electronic structure and reactivity of transition metal complexes with Professor Theodore Betley of Harvard University and Professor Kyle Lancaster of Cornell University. The overarching goals of the 3-year project, which began on July 15, 2023, are to explore how metal-ligand compositions and changing oxidation levels alter the physical properties...
This $575,000 Project Grant awarded by the National Science Foundation (NSF) Division of Chemistry will support Purdue University's research into photoactive iron and cobalt organometallic compounds. Led by Professor Tong Ren, the team will investigate a new family of macrocycle-supported metal complexes to extend the lifetimes of excited states and improve the efficiency of solar energy utilization. Key objectives include synthesizing Fe(II)-TIM and Fe(III)-TIM complexes as new...
This $450,000 National Science Foundation project grant supports research at Cornell University from August 2022 to July 2025 under the Mathematical and Physical Sciences program (CFDA 47.049). Principal Investigator Kyle Lancaster and his team are developing new classes of two- and pseudo-one-coordinate transition metal complexes with applications as catalysts and for data storage technologies. Specifically, the researchers aim to synthesize hetero-leptic transition metal complexes using...
This $550,000 National Science Foundation project grant supports research into the role of non-covalent interactions in the excited state dynamics of heterocyclic compounds. Funded under the NSF's Mathematical and Physical Sciences program (CFDA 47.049), Professor de Vries at the University of California, Santa Barbara will experimentally study how such compounds respond to ultraviolet radiation using gas phase spectroscopy. Computational chemists will model the results to compare quantum...

This $545,000 project grant from the National Science Foundation's Mathematical and Physical Sciences program, specifically the Division of Chemistry, will fund research into ultrafast dynamics occurring in the ground states of transition metal complexes being conducted by Professor Clifford Kubiak of the University of California, San Diego from August 1, 2022 to July 31, 2025.

The research aims to develop new assemblies of metal complexes that undergo fast electron transfer reactions through investigating a new generation of mixed-valent complexes. Findings could extend to integrated circuits, quantum computing, and artificial photosynthesis. Professor Kubiak's group also engages K-12 and undergraduate students in the cutting-edge fundamental science. Previous support informed key future research areas including measuring influences of electric fields on mixed-valent complexes, driving chemical reactions important to catalysis with electric fields, understanding interactions between chiral molecules and spin using chiral bridges, and preparing/studying high-spin mixed-valent iron clusters.

Generated 1/7/24, 2:57 AM