D2_Safety_Data_Sheet.pdf

Supersedes Revision: 02/04/2015

1. Product and Company Identification

Product Code:

Product Name:

Company Name:

Web site address:

00400

D/2 Biological Solution

D/2 Biological Solution, Inc.

PO Box 3746

Westport, MA 02790 d2bio.com

Phone Number:

(917)693-7441

Emergency Contact: Chem-Tel (800)255-3924

Recommended Use: Removal of stains from mold, algae, mildew, lichen and air pollutants. Effective on marble, granite, limestone, travertine, brownstone, masonry, stucco, wood, canvas and other architectural surfaces.

Intended Use: For sale to, use and storage by service persons only.

Additional Information: Additional Product Codes: 00401, 00402

2. Hazards Identification

Skin Corrosion/Irritation, Category 3

Serious Eye Damage/Eye Irritation, Category 2B

Acute Toxicity: Oral, Category 4

Warning

Causes mild skin irritation.

Causes eye irritation.

Harmful if swallowed.

Do not eat, drink or smoke when using this product.

Keep out of reach of children.

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Rinse mouth.

If swallowed: Call a Poison Center or doctor if you feel unwell.

If on skin (or in hair): Wash with plenty of soap and water.

Store in cool dry place at room temperature away from direct sunlight.

Dispose of contents and container according to the local, city, state and federal regulations.

Chronic: Effects may be delayed.

May be harmful if inhaled. Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Inhalation of dust may cause respiratory tract irritation. Can produce delayed pulmonary edema. Causes irritation of the mucous membrane and upper respiratory tract.

May be harmful if absorbed through the skin. Causes skin irritation.

Causes eye irritation. May cause chemical conjunctivitis.

May be harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.

SAFETY DATA SHEET

D/2 Biological Solution

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Revision: 5/30/15

GHS Signal Word:

GHS Hazard Phrases:

GHS Precaution Phrases:

GHS Response Phrases:

GHS Storage and Disposal

Phrases:

Potential Health Effects

(Acute and Chronic):

Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

3. Composition/Information on Ingredients

CAS # Chemical Name Concentration

7173-51-5 1-Decanaminium, N-Decyl-N,N-dimethyl-, chloride Proprietary

29911-27-1 2-Propanol, 1-(1-methyl-2-propoxyethoxy)- Proprietary

7396-58-9 Didecylamine, N-methyl- Proprietary

4. First Aid Measures

Emergency and First Aid

Procedures:

Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid.

Wash off with soap and plenty of water. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Rinse thoroughly with plenty of water for at least 15 minutes. Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Consult a physician.

Never give anything by mouth to an unconscious person. Rinse mouth with water. Do

NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Consult a physician.

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Show this safety data sheet to the doctor in attendance. Move out of dangerous area.

Treat symptomatically and supportively.

5. Fire Fighting Measures

N / A

Flash Pt: NE

Explosive Limits: LEL: N/A UEL: N/A

Autoignition Pt: NE

Suitable Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Fire Fighting Instructions:

Flammable Properties and

Hazards:

Wear self contained breathing apparatus for fire fighting if necessary. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion.

No data available.

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Revision: 05/30/2015

In Case of Inhalation:

In Case of Skin Contact:

In Case of Eye Contact:

In Case of Ingestion:

Signs and Symptoms Of

Exposure:

Note to Physician:

6. Accidental Release Measures

Steps To Be Taken In Case

Material Is Spilled:

Personal precautions.

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.

Environmental precautions.

Do not let product enter drains.

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container.

Clean up spills immediately, observing precautions in the Protective Equipment section.

Avoid generating dusty conditions.

7. Handling and Storage Handle in accordance to good industrial safety practice and hygiene.

Keep container tightly closed in a dry and well-ventilated place. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Store protected from moisture.

Keep container tightly closed in a dry, well ventilated place away from incompatible substances (Oxidizing Agents and Chlorinated Compounds). Keep out of reach of children.

8. Exposure Controls/Personal Protection

Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the specific region regulatory bodies.

Engineering Controls Eyewash station and shower.

General Hygiene Handle in accordance with good industrial safety and hygiene standards. Wash hands before break and at end of the day. Do not smoke.

Eye & Face Protection Wear safety goggles with side protection conforming to EN 166.

Skin & Body Protection Wear protective gloves and clothing.

Respiratory Protection If irritation is experienced or exposure limits are exceeded use a respirator that complies with appropriate government standards such as NIOSH (US) or CEN (EU).

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Precautions To Be Taken in Handling:

Precautions To Be Taken in Storing:

9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid

Appearance and Odor: Colorless liquid with herbal odor.

Melting Point: NE

Boiling Point: > 212.00 F

Freezing Point: 16 F

Decomposition Temperature: NE

Autoignition Pt: NE

Flash Pt: NE

Explosive Limits: LEL: N/A UEL: N/A

Specific Gravity (Water = 1): 1.020

Density: 8.50 LB/GA

Bulk density: NE

Vapor Pressure (vs. Air or NE mm Hg):

Vapor Density (vs. Air = 1): > 1

Evaporation Rate: NE

Solubility in Water: 100%

Saturated Vapor NE

Concentration:

Viscosity: NP pH: 9.0 - 10.0

Percent Volatile: No data.

VOC / Volume: 0.0000 G/L

Particle Size: NE

Heat Value: NE

Corrosion Rate: NE

10. Stability and Reactivity

Stability: Unstable [ ] Stable [ X ]

Conditions To Avoid -

Instability:

No data available.

Incompatible materials.

Incompatibility - Materials To Strong oxidizing agents, Strong acids, Strong bases, Ammonia, magnesium, Sodium, Avoid: calcium salts.

Hazardous Decomposition Or Thermal decomposition can lead to irritating and toxic fumes and gases

Byproducts:

Possibility of Hazardous Will occur [ ] Will not occur [ X ]

Reactions:

Conditions To Avoid - None.

Hazardous Reactions:

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11. Toxicological Information Acute toxicity. No data available.

Respiratory or skin sensitization: Germ cell mutagenicity. Reproductive toxicity - no data available.

Specific target organ toxicity -single exposure (Globally Harmonized System)

Specific target organ toxicity -repeated exposure (Globally Harmonized System)

Aspiration hazard. Epidemiology: No information found.

Teratogenicity: No information available. Reproductive Effects: Mutagenicity:

Neurotoxicity:

CAS# 68439-46-3:

Acute toxicity, LD50, Oral, Rat, 1378. MG/KG.

Results:

Vascular:Measurement of regional blood flow.

Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels:

Dehydrogenases.

Biochemical: Metabolism (Intermediary): Lipids including transport.

- Journal of the American College of Toxicology., Mary Ann Liebert, Inc., New York, NY, Vol/p/yr: 10(4),427, 1991

CAS# 7320-34-5:

Acute toxicity, LD50, Skin, Species: Rabbit, 4640. MG/KG.

Results:

Paternal Effects: Testes, epididymis, sperm duct.

- National Technical Information Service, Vol/p/yr: OTS0571153, No data available.

Carcinogenicity.

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. CAS# 7320-34-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

NTP? No IARC Monographs? No OSHA Regulated? No

12. Ecological Information

No data available.

Results of PBT and vPvB assessment:

Persistence and

Degradability:

CAS# 68439-46-3:

LC50, Fathead Minnow (Pimephales promelas), 11000. UG/L, 96 H, Mortality, Water temperature: 22.00 C C.

Results:

Morphological changes.

- Acute Toxicity and Structure-Activity Relationships of Nine Alcohol Ethoxylate

Surfactants to Fathead Minnow and Daphnia magna, Wong, D.C.L., P.B. Dorn, and E.Y.

Chai, 1997

No data available.

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Toxicological Information:

Irritation or Corrosion:

Carcinogenicity/Other

Information:

Carcinogenicity:

Bioaccumulative

Potential: No data available

Mobility in Soil: No data available.

13. Disposal Considerations Waste Disposal Method: Product.

Observe all federal, state, and local environmental regulations.

Do not reuse container.

14. Transport Information

LAND TRANSPORT (US DOT):

DOT Proper Shipping Name: Not regulated as a hazardous material.

DOT Hazard Class:

UN/NA Number:

LAND TRANSPORT (Canadian TDG):

TDG Shipping Name: Not Regulated.

MARINE TRANSPORT (IMDG/IMO):

IMDG/IMO Shipping Name: Not Regulated.

AIR TRANSPORT (ICAO/IATA):

ICAO/IATA Shipping Name: Not Regulated.

15. Regulatory Information

EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists

CAS # Chemical Name S. 302 (EHS) S. 304 RQ S. 313 (TRI)

7173-51-5 1-Decanaminium, N-Decyl-N,N-dimethyl-, chloride No No No

29911-27-1 2-Propanol, 1-(1-methyl-2-propoxyethoxy)- No No No

7396-58-9 Didecylamine, N-methyl- No No No

CAS # Chemical Name Other US EPA or State Lists

7173-51-5 1-Decanaminium, N-Decyl-N,N-dimethyl-, chloride CA PROP.65: No; CA TAC, Title 8: No

29911-27-1 2-Propanol, 1-(1-methyl-2-propoxyethoxy)- CA PROP.65: No; CA TAC, Title 8: No 7396-58-9 Didecylamine, N-methyl- CA PROP.65: No; CA TAC, Title 8: No

U.S. Federal Regulations SARA 302, 304, 313 Superfund Amendment and Reauthorization Act of 1986 In compiiance CA PROP. 65 California Proposition 65 In compliance CWA Clean Water Act In compliance CERCLA Comprehensive Environmental Response and Compensation Act In compliance

International Regulations TSCA U.S. Toxic Substance Control Act Section 8(b) Inventory In compliance DSL/NDSL Canadian Domestic Substance List/Non Domestic Substance List In compliance

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16. Other Information Hazard Rating System:

HMIS:

Revision Date: 05/01/2015

Additional Information About No data available.

This Product:

Company Policy or

Disclaimer:

The manufacturer believes the data set forth are accurate and makes no warranty with respects thereto and disclaims all liability for reliance thereon. Such data are offered solely for consideration, investigation and verification. Also, the data set forth is for the concentrated finished product. All lab samples are for experimental purposes only and used at the customers discretion.

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Revision 05/30/2015

HEALTH 1

FLAMMABILITY 0

B

PHYSICAL

PPE

Health

NFPA: Special Hazard

Flammability Instability

1 0