SDS_for_Squibs_0001.pdf

SAFETY DATA SHEET

Replacement Squib Cartridge

Revision Date: April 10, 2015 Page 1 of 7

1. IDENTIFICATION

Product Name Replacement Squib Cartridge Other Trade Names Squib Charge Product Numbers 83-844712-000, 83-897391-000 Recommended use of the chemical and restrictions on use

Identified uses Electro - pyrotechnic device

Restrictions on use Not user serviceable. Do not attempt downloading or disassembling.

Company Identification Kidde-Fenwal, Inc.

400 Main Street Ashland, MA 01721

USA

Customer Information Number (508) 881-2000 Emergency Telephone Number

CHEMTREC Number (800) 424-9300

(703) 527-3887 (International)

Issue Date April 10, 2015

Supersedes Date February 9, 2012

Safety Data Sheet prepared in accordance with OSHA’s Hazard Communication Standard (29 CFR 1910.1200)and the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2. HAZARD IDENTIFICATION

Hazard Classification

Explosives – Division 1.4

Label Elements Hazard Symbols

Signal Word: Warning

Hazard Statements Fire or projection hazard

Precautionary Statements

Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

Ground/bond container and receiving equipment.

Do not subject to grinding/shock/friction.

Wear face protection.

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2. HAZARD IDENTIFICATION

Response In case of fire: Evacuate area.

Explosion risk in case of fire.

Do NOT fight fire when fire reaches explosives.

Fight fire with normal precautions from a reasonable distance.

Storage Store in accordance with local regulations.

Disposal

Dispose of contents/container in accordance with local regulation.

Other Hazards

None identified.

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is a mixture contained in a sealed device.

Component CAS Number Concentration Cyclotrimethylenetrinitramine 121-82-4 NA Diphenylamine 122-39-4 NA Nitrocellulose 9004-70-0 NA Potassium Perchlorate 7778-74-7 NA Titanium 7440-32-6 NA

Note: Net reactive material content is 0.350 grams per unit.

4. FIRST- AID MEASURES

Description of necessary first-aid measures

Eyes No specific treatment is required as exposure is unlikely under normal conditions of use.

Skin No specific treatment is required as exposure is unlikely under normal conditions of use.

Ingestion No specific treatment is required as exposure is unlikely under normal conditions of use.

Inhalation No specific treatment is required as exposure is unlikely under normal conditions of use.

Most important symptoms/effects, acute and delayed Aside from the information found under Description of necessary first aid measures (above) and Indication of immediate medical attention and special treatment needed, no additional symptoms and effects are anticipated.

Indication of immediate medical attention and special treatment needed

Notes to Physicians Treat symptomatically.

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5. FIRE - FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing agent appropriate to other materials involved. Keep containers and surroundings cool with water spray as containers may explode in the heat of a fire.

Specific hazards arising from the chemical Do not fight fires involving explosives. Product may explode. Evacuate the area and allow to burn or fight fire remotely. May release toxic fumes during a fire.

Special Protective Actions for Fire-Fighters Wear full protective clothing and self-contained breathing apparatus as appropriate for specific fire conditions.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures If cartridges are spilled from their shipping or storage container and are damaged, cordon off the area until the situation has been properly assessed. Wear appropriate protective clothing to shield from accidental detonation.

Environmental Precautions None

Methods and materials for containment and cleaning up Recover the cartridges by hand and inspect in a shielded area before repacking. Dispose of damaged cartridges. If cartridge has ruptured: clean spill after liberally wetting down with solvent (acetone, butyl acetate or alcohol) by wiping material up with paper towel or cotton rag. Keep a fire extinguisher present.

7. HANDLING AND STORAGE

Precautions for safe handling Wear appropriate protective clothing. Work with device in a shielded area, keep shunted until installed.

Conditions for safe storage Keep away from friction, impact, heat, flame, radio transmitters, electric storms and electric currents, including those caused by static electricity. Store in original packaging at 70oF. Keep away from other explosives. Do not disassemble cartridges as this may cause them to explode.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters Exposure limits are listed below, if they exist.

Cyclotrimethylenetrinitramine ACGIH: TLV 0.5 mg/m3 8h TWA. Danger of cutaneous absorption.

Diphenylamine ACGIH: TLV 10 mg/m3 8h TWA

Revision Date: April 10, 2015 Page 4 of 7

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Appropriate engineering controls Work with device in a shielded area. Keep shunted until installed.

Individual protection measures

Respiratory Protection Not normally required.

Skin Protection Cotton gloves

Eye/Face Protection Chemical goggles or safety glasses with side shields.

Body Protection Cotton clothing and conductive-soled shoes.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Physical State Solid

Color N/A

Odor None

Odor Threshold Not applicable pH Not applicable

Specific Gravity Not applicable

Boiling Range/Point (°C/F) Not applicable

Melting Point (°C/F) Not applicable

Flash Point (PMCC) (°C/F) Not applicable

Vapor Pressure Not applicable

Evaporation Rate (BuAc=1) Not applicable

Solubility in Water Not applicable

Vapor Density (Air = 1) Not applicable

VOC (g/l) Not applicable

VOC (%) Not applicable

Partition coefficient (n-octanol/water)

Not applicable

Viscosity Not applicable

Auto-ignition Temperature 250 oF

Decomposition Temperature No data available

Upper explosive limit Not applicable

Lower explosive limit Not applicable

Flammability (solid, gas) No data available

10. STABILITY AND REACTIVITY

Reactivity No data available

Chemical Stability Stable under normal conditions but improper handling can result in accidental detonation.

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10. STABILITY AND REACTIVITY

Possibility of hazardous reactions Hazardous polymerization will not occur.

Conditions to Avoid Exposure to low level electric current - impact - heat- static - shock - radio frequency (RF) energy

Incompatible Materials None known

Hazardous Decomposition Products Oxides of carbon – nitrogen oxides – hydrogen cyanide – hydrochloric acid – titanium oxides

11. TOXICOLOGICAL INFORMATION

This product is a sealed device preventing exposure to the components inside. The information below is applicable only if the cartridges rupture before use.

Acute Toxicity Cyclotrimethylenetrinitramine: LD50 oral (rat) 100mg/kg Diphenylamine: LD50 oral (rat) 2000 mg/kg

Specific Target Organ Toxicity (STOT) – single exposure Cyclotrimethylenetrinitramine: Causes damage to the central nervous system (route of exposure: oral)

Specific Target Organ Toxicity (STOT) – repeat exposure Diphenylamine: May cause damage to organs (hematological system, kidneys, spleen, liver) through prolonged or repeated exposure (route of exposure: oral).

Cyclotrimethylenetrinitramine: May cause damage to organs (central nervous system) through prolonged or repeated exposure (route of exposure: oral).

Serious Eye damage/Irritation Diphenylamine: Causes serious eye irritation.

Skin Corrosion/Irritation No relevant studies identified.

Respiratory or Skin Sensitization

Carcinogenicity

Germ Cell Mutagenicity

Reproductive Toxicity

Aspiration Hazard Not an aspiration hazard.

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12. ECOLOGICAL INFORMATION

Ecotoxicity Cyclotrimethylenetrinitramine: LC50 Daphnia magna (Water flea) >15 mg/L/96 hr Diphenylamine: LC50 Brachydanio rerio (Zebrafish) 2.2 mg/L/48hr

Mobility in soil

Persistence/Degradability

Bioaccumulative Potential

Other adverse effects

13. DISPOSAL CONSIDERATIONS

Disposal Methods This material should be disposed of in accordance with all applicable local and national regulations.

14. TRANSPORT INFORMATION

Safety Data Sheet information is intended to address a specific material and not various forms or states of containment. Specific volumes, pressures or hardware configurations containing such materials can dictate various different hazard classifications for transportation and labelling requirements. Under Federal Regulations only trained and qualified individuals are permitted to label and ship products following the applicable Department of Transportation (DOT), Federal Aviation Administration (FAA), Transport Canada (TC), International Maritime Dangerous Goods (IMDG) or International Air

Transport Association (IATA) requirements.

15. REGULATORY INFORMATION

United States TSCA Inventory This product contains ingredients that are listed on or exempt from listing on the EPA Toxic Substance Control Act Chemical Substance Inventory.

Canada DSL Inventory All ingredients in this product are listed on the Domestic Substance List (DSL) or the Non-Domestic Substance List (NDSL) or are exempt from listing.

SARA Title III Sect. 311/312 Categorization Pressure Hazard (Explosive)

SARA Title III Sect. 313 This product contains the following chemicals listed in Section 313 at or above de minimis concentrations Diphenylamine (122-39-4)

Revision Date: April 10, 2015 Page 7 of 7

16. OTHER INFORMATION

Legend ACGIH: American Conference of Governmental Industrial Hygienists CAS#: Chemical Abstracts Service Number ECHA: European Chemicals Agency EC50: Effect Concentration 50% IARC: International Agency for Research on Cancer LC50: Lethal Concentration 50% LD50: Lethal Dose 50% N/A: Denotes no applicable information found or available OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit STEL: Short Term Exposure Limit TLV: Threshold Limit Value TSCA: Toxic Substance Control Act

Revision Date: April 10, 2015 Replaces: February 9, 2012 Changes made: Updated to GHS Classification.

Information Source and References This SDS is prepared by Hazard Communication Specialists based on information provided by internal company references.

Prepared By: EnviroNet LLC.

The information and recommendations presented in this SDS are based on sources believed to be accurate. Kidde-Fenwal, Inc. assumes no liability for the accuracy or completeness of this information. It is the user's responsibility to determine the suitability of the material for their particular purposes. In particular, we make NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, with respect to such information, and we assume no liability resulting from its use. Users should ensure that any use or disposal of the material is in accordance with applicable Federal, State, and local laws and regulations.