Project Grant 2505971
- The National Science Foundation Division of Chemistry awarded a $465,000 Project Grant to the University of North Carolina at Chapel Hill under the Mathematical and Physical Sciences federal grant program (CFDA 47.049) to support research into carbodiimide ring-opening metathesis polymerization for the precise synthesis of nitrogen-rich polymer backbones from July 1, 2022 to June 30, 2025. The university, working with Principal Investigator Aleksandr Zhukhovitskiy, will utilize iridium metal...
- This Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences Federal Grant Program (CFDA 47.049) will fund collaborative research by Dr. Aleksandr Zhukhovitskiy at the University of North Carolina at Chapel Hill and Dr. Ian Tonks at the University of Minnesota-Twin Cities. The $420,000 award from September 1, 2024 to August 31, 2027 will develop catalytic methods to edit the molecular architectures of various plastics such as polyesters and...
- Through this $699,254 Project Grant awarded by the National Science Foundation's Division of Chemistry under the Mathematical and Physical Sciences program (CFDA 47.049), Professor Eugene Y. Chen of Colorado State University is developing new synthetic routes for the construction of technologically important cyclic polymers and copolymers from bio-based renewable monomers. The project aims to precisely control the structures and sequences of these cyclic polymers and copolymers using Lewis...
- This $300,000 Project Grant awarded by the National Science Foundation (NSF) Division of Chemistry aims to develop novel polymeric materials based on segmented polar-polyolefin copolymers with complex architectures. Professors Eva Harth at the University of Houston and Krzysztof Matyjaszewski at Carnegie Mellon University are collaborating on this 3-year effort, which seeks to advance energy storage materials and plastic upcycling capabilities. The key products and services to be delivered...
- The National Science Foundation (NSF) Division of Chemistry awarded a $652,777 Project Grant under the Mathematical and Physical Sciences program (CFDA 47.049) to the University of North Carolina at Chapel Hill. Through this 4-year grant, Professor Erik J. Alexanian is developing chemical reagents to enable the selective diversification of polyolefin plastics, such as polyethylene and polypropylene, through C-H bond functionalization. This approach aims to "upcycle" post-consumer...
- This $118,229 National Science Foundation (NSF) grant under the Mathematical and Physical Sciences (CFDA 47.049) program supports the development of novel, chemically recyclable polymer materials at the University of New Haven. The project aims to design low-strain cyclic olefin monomers that can be polymerized and then easily depolymerized back to their constituent monomers under mild conditions, addressing the energy-intensive nature of current polymer recycling methods. Through this 5-year...
- This three-year, $274,094 National Science Foundation project grant supports collaborative research between Duke University and the University of South Carolina to develop metal-containing polymers that respond chemically to mechanical stress. Funded through NSF's Mathematical and Physical Sciences program (CFDA 47.049), the researchers aim to establish structure-activity relationships and reaction mechanisms for mechanochemical cleavage of metal-cyclopentadienyl bonds. They will synthesize...
- This National Science Foundation project grant of $598,000 supports research at Cornell University from September 2022 through August 2026 under the Mathematical and Physical Sciences program (CFDA 47.049). Brett P. Fors will develop new photoinitiated polymerization strategies using common functional groups to produce polymers with controlled structures. Specifically, the research will utilize photocatalysis to directly initiate radical polymerization from carboxylic acids and C-H bonds,...
- The National Science Foundation (NSF) Division of Chemistry awarded a $570,000 Project Grant to Yale University under the Mathematical and Physical Sciences (CFDA 47.049) program. The grant supports the "Design of Lewis Acid Tethered Chain-End Capping Agents for Stereocontrolled Radical Polymerization" research project led by Dr. Mingjiang Zhong. The project aims to develop innovative catalytic systems to achieve stereocontrolled radical polymerization, which can produce polymeric...
- This $210,335 NSF Mathematical and Physical Sciences (CFDA 47.049) Project Grant award to Drexel University supports the development of a new computational method to accelerate the design of new polymeric materials. The project aims to create a simulation technique that can simultaneously resolve both monomer-level chemistry and mesoscopic length scales within polymeric materials. This has the potential to significantly speed up the development of new polymers for diverse applications like...
Under a $600,000 Project Grant award from the National Science Foundation's (NSF) Mathematical and Physical Sciences program (CFDA 47.049), Dr. Aleksandr V. Zhukhovitskiy of the University of North Carolina at Chapel Hill is developing new methods to prepare polymeric materials with a high content of nitrogen atoms embedded within the polymer chains. The research seeks to improve the precision of the ring-opening polymerization of cyclic carbodiimides, as well as to develop alternative transition metal catalysts for this process. Additionally, the lessons learned from the carbodiimide polymerization will be extended to new nitrogen-containing molecules to ultimately access structurally precise photo-responsive plastics. This research combines experimental and computational components at the interface of polymer, organometallic, and physical organic chemistry, with the goal of advancing sustainable and versatile polymeric materials.
Mod # | Description | ReasonForModification | Federal Obligation | Date |
|---|---|---|---|---|
| Not listed | $600.0k | 8/15/25 |