Project Grant 2448927
- The National Science Foundation (NSF) awarded a $575,000 project grant under its Mathematical and Physical Sciences (MPS) program to the University of Wisconsin-Madison to study the use of light in organic synthesis. Under this 3-year award effective July 1, 2024, Professor Tehshik Yoon and his team will design novel photocatalysts that can interact directly with small molecules to control how they react and form more complex products. The research aims to transform discovery in pharmaceutical...
- Professor Kutateladze of the University of Denver will use a $575,000 National Science Foundation Project Grant from the Mathematical and Physical Sciences program (CFDA 47.049) to further develop photoassisted approaches for the synthesis of complex heterocyclic molecules with potentially useful therapeutic properties. Over a three-year period from September 2023 through August 2026, his research aims to expand the synthetic photochemistry toolbox, specifically excited state intramolecular...
- The National Science Foundation (NSF) Chemical Synthesis Program has awarded a $550,000 Project Grant to Professor Jon Njardarson of the University of Arizona. The grant supports the development of new asymmetric anionic reaction cascades that leverage readily available feedstock materials and negatively charged reaction partners to produce higher-value fine chemical products. Key objectives include in situ trapping of lithium enamides to expand product types, as well as the formation of...
- The National Science Foundation (NSF) Chemical Synthesis Program awarded a $450,000 Project Grant to Professor William Chain at the University of Delaware (UDE) to develop new classes of reactions with aromatic compounds. The goal is to exploit weak bonds and temporarily elevate the reactivity of normally inert chemical compounds to facilitate the formation of a wide array of new carbon-based bonds, forging new cyclic frameworks that have applications in industrial, chemical, and medical...
- Under a $293,308 Project Grant awarded by the National Science Foundation (NSF) Division of Chemistry through the Mathematical and Physical Sciences program (CFDA 47.049), Purdue University is conducting research to develop new chiral catalysts for enantioselective photoredox-catalyzed carbon-carbon bond-forming reactions. The project aims to design efficient photochemical reactions to synthesize specific enantiomers of chiral organic molecules, which have important applications in...
- This $519,028 federal Project Grant award from the National Science Foundation's Mathematical and Physical Sciences (CFDA #47.049) program supports research by Professor Jayaraman Sivaguru and his team at Bowling Green State University. The goal is to discover new and productive photochemical pathways that can enable sustainable chemical synthesis. The research aims to (i) uncover novel photochemical reactivity, (ii) employ modern photochemical tools to develop knowledge about excited state...
- This three-year, $440,000 Project Grant from the National Science Foundation's Division of Chemistry will support research into controlling the selectivity of photochemical reactions through the use of aligning media and plane-polarized light. Professor Evgueni Nesterov of Northern Illinois University will investigate a novel method for tuning photochemistry with polarized light, which has the potential to control reaction pathways and selectivity by uniformly aligning photoreactive compounds...
- This $199,125 project grant awarded by the National Science Foundation's (NSF) Mathematical and Physical Sciences program (CFDA 47.049) is funding a collaborative research effort between the University of Cincinnati and the University of Kansas to develop advanced photocatalysts that can be activated by near-infrared (NIR) light. The research team, led by Professor Yujie Sun and Professor Christopher Elles, is designing and synthesizing novel molecular chromophores with enhanced two-photon...
- The National Science Foundation (NSF) Division of Chemistry awarded a $550,000 Project Grant under the Mathematical and Physical Sciences (CFDA 47.049) program to the University of North Carolina at Chapel Hill (UNC-CH) for a 3-year project. The objective is to establish light-activated reactions that form transition metal hydride complexes, which are critical for producing fuels and commodity chemicals. The research activities will study the electronic structure and photochemistry of...
- The National Science Foundation (NSF) awarded a $198,641 Project Grant to Virginia Polytechnic Institute & State University (Virginia Tech) under the Mathematical and Physical Sciences (CFDA 47.049) federal grant program. The purpose of this 4-year grant is to support the development of a new class of photocatalysts that can selectively oxidize inexpensive raw materials into value-added chemicals using light energy and ambient oxygen as sustainable reagents. The research aims to control...
The National Science Foundation (NSF) Chemical Synthesis Program awarded a $575,000 Project Grant to the University of Kansas Center for Research Inc. to develop new photochemical reactions for creating valuable and structurally complex molecules efficiently and selectively. The project, titled "Exploiting Mechanistic Knowledge to Develop Selective and Robust Synthetic N,π*-Star Photochemistry," aims to (1) generate reactive ylides from strained rings through light-induced sensitized decarbonylation, (2) control the stereochemistry of nitrogen-containing molecules to make four-membered azetidine rings, and (3) study short-lived radical intermediates using advanced spectroscopic techniques. The research will leverage visible light activation, custom-designed light-absorbing groups, and chiral anions/auxiliaries to control chemical reactivity, with computational modeling to explain and predict reaction behavior. This project will also develop educational tools and preserve a collection of previously synthesized compounds for future research.
Mod # | Description | ReasonForModification | Federal Obligation | Date |
|---|---|---|---|---|
| Not listed | $575.0k | 7/29/25 |