This $550,000 Project Grant award from the National Science Foundation (NSF) Technology, Innovation, and Partnerships (TIP) program (CFDA 47.084) aims to develop and commercialize a borane compound with high thermal stability and a unique chemical structure. The key product is tris(ortho-carboranyl)borane, which can serve as a catalyst or reagent with enhanced reactivity compared to existing boranes on the market. The research will optimize the synthesis process, scale up production to the...
The National Science Foundation (NSF) awarded a Project Grant of $424,847 to Baylor University to support the "Design, Synthesis, and Reactivity of Diboryl- and Aminoboryl Carbenes" research project under the Mathematical and Physical Sciences (CFDA 47.049) federal grant program. This high-risk, high-reward effort aims to utilize synthetic methodologies developed by the principal investigator to prepare previously unknown carbene compounds containing two boron atoms bonded to the...
This $285,919 Project Grant awarded by the National Science Foundation's (NSF) Division of Materials Research supports research at Baylor University focused on the flux-mediated synthesis of metastable Cu(I)-containing semiconductor materials. The goal is to advance capabilities for preparing crystalline solids with technologically useful properties, particularly for applications in solar energy capture and catalytic carbon dioxide reduction. The research involves structural characterization,...
This three-year, $353,871 Project Grant from the National Science Foundation's Division of Chemical, Bioengineering, Environmental, and Transport Systems, under the Engineering program (CFDA 47.041), will fund research at Baylor University to develop molecular assemblies directed by halogen bonding and other noncovalent interactions. The university will characterize molecular properties of halogen bond donors and acceptors, assess stability and bond strengths, and direct the assembly of two- and...
Professor Zachary Ball at Rice University will receive $531,000 from the National Science Foundation Division of Chemistry under the Mathematical and Physical Sciences federal grant program (CFDA 47.049) to develop new methods for selective chemical manipulation of biomacromolecules using boronic acids. Over a three-year period from September 1, 2022 to August 31, 2025, the project will explore boronic acids as cross-coupling reagents for new carbon-carbon and carbon-heteroatom bond formation...
The National Science Foundation (NSF) awarded a $176,349 Project Grant under the Integrative Activities program (CFDA 47.083) to the University of Iowa to develop borenium-based ligands that enable tandem catalytic reactions with transition metals. This innovative research aims to create multifunctional metallo-boron complexes capable of performing two distinct catalytic transformations using a single metal catalyst, which could lead to more efficient and cost-effective methods for...
Professor Daniel Romo of Baylor University will utilize $1,070,000 in funding from the National Science Foundation's Mathematical and Physical Sciences program (CFDA 47.049) over a three year period from July 2022 to June 2025. The project aims to advance the development of novel organocatalytic cascade and domino reaction processes for rapidly constructing structurally complex molecules relevant to bioactive natural products and pharmaceutical synthesis. Specifically, the funding will support...
This Project Grant award from the National Science Foundation (NSF) Mathematical and Physical Sciences program (CFDA 47.049) provides $211,772 to Professor Liela Romero at Baylor University to develop new strategies for chemical synthesis using early transition metal catalysts. The key objectives are to: 1) advance the fundamental chemistry of Group IV transition metals, 2) expand the utility of metal hydride catalysis, and 3) create innovative synthetic tools. The grant supports research to...
The National Science Foundation (NSF) awarded Purdue University a $575,000 Project Grant under the Mathematical and Physical Sciences (CFDA 47.049) federal grant program. The grant supports Professor Christopher Uyeda's research on developing multi-metallic catalysts to improve the efficiency and sustainability of chemical processes used in medicine, agriculture, and polymer chemistry. Key activities include designing new ligands that can bind multiple metals to create more active and...
Baylor University received a $162,045 Project Grant award from the National Science Foundation Division of Materials Research under the Mathematical and Physical Sciences program (CFDA 47.049) for the period of February 1, 2022 through September 30, 2022. The grant funds research into discovering new metal-based compounds and linking their chemical structures to magnetic, electrical, and thermal properties for energy applications. Specifically, the principal investigator will grow large single...